Synthesis and Characterization of Au/ Sb 2 O 3 Ultrathin nanosheet/Au as a High-Performance UV-Photodetector

Authors

  • Nageb T. Rassam Department of Technical Information System Engineering, Erbil Technical Engineering College, Erbil Polytechnic University -Erbil, Iraq

DOI:

https://doi.org/10.25156/ptj.v12n1y2022.pp155-162

Keywords:

Sb 2 O 3, Ultrathin nanosheets, Au/Sb 2 O 3 /Au, MSM UV-photodetector

Abstract

Ultrathin antimony trioxide (Sb 2 O 3 ) was synthesized on ITO substrate by solvothermal method using ethanol as a
solvent. The structure, morphological variations and optical properties of the as-prepared sample were characterized.
The results indicated that the homogeneously grown sheet of cubic phase of ultrathin Sb 2 O 3 have elliptical cross
section with thickness of 20 nm and diameter of 400-500 nm. Further, an ultraviolet (UV) performance
photodetector based on the (Au/Sb 2 O 3 /Au) was fabricated and examined. The measured Current Voltage (IV) curves
in the dark and under illumination (UV-395 nm) of different intensities indicate the presence of Schottky barrier at
the interfaces between Sb 2 O 3 and Au-electrodes. Photocurrent values of 2.32, 16.5, and 25.58 μA were obtained for
intensities of 4, 8 and 12 mW/cm 2 , respectively at bias voltage of +3V, as compared to dark current of 0.78μA.
Sensitivity and responsivity values of 40.04 and 6.294W/A were recorded. The current-time (I-T) graph was utilized
to derive the response and recovery times of the sensor under chopped UV-laser at different power intensities. The
sensor exhibited fast response and recovery times of 113.6 ms and 67.2 ms, respectively, making this a high-
performance sensor. This study demonstrates that ultrathin Sb 2 O 3 nanosheet can be very useful to develop simple
and high-performance UV sensors in different commercial fields and industries in the future.

Downloads

Download data is not yet available.

References

N. N. Jandow, H. A. Hassan, F. K. Yam, and K. Ibrahim, ZnO Metal-Semiconductor-Metal UV Photodetectors on PPC Plastic with Various Metal Contacts, Photodetectors 1 (2012).

A. F. Abdulrahman, S. M. Ahmed, A. A. Barzinjy, S. M. Hamad, N. M. Ahmed, and M. A. Almessiere, Fabrication and Characterization of High-Quality UV Photodetectors Based ZnO Nanorods Using Traditional and Modified Chemical Bath Deposition Methods, Nanomaterials 11, 677 (2021).

J. C. Carrano, P. A. Grudowski, C. J. Eiting, R. D. Dupuis, and J. C. Campbell, Very Low Dark Current Metal--Semiconductor--Metal Ultraviolet Photodetectors Fabricated on Single-Crystal GaN Epitaxial Layers, Appl. Phys. Lett. 70, 1992 (1997).

L. Qi, K. R. C. Mok, M. Aminian, E. Charbon, and L. K. Nanver, UV-Sensitive Low Dark-Count PureB Single-Photon Avalanche Diode, IEEE Trans. Electron Devices 61, 3768 (2014).

B. Pandit and J. Cho, AlGaN Ultraviolet Metal--Semiconductor--Metal Photodetectors with Reduced Graphene Oxide Contacts, Appl. Sci. 8, 2098 (2018).

H. Chang, D. H. Lee, H. S. Kim, J. Park, and B. Y. Lee, Facile Fabrication of Self-Assembled ZnO Nanowire Network Channels and Its Gate-Controlled UV Detection, Nanoscale Res. Lett. 13, 1 (2018).

X. Sun, F. Azad, S. Wang, L. Zhao, and S. Su, Low-Cost Flexible ZnO Microwires Array Ultraviolet Photodetector Embedded in PAVL Substrate, Nanoscale Res. Lett. 13, 1 (2018).

X. Liu, L. Gu, Q. Zhang, J. Wu, Y. Long, and Z. Fan, All-Printable Band-Edge Modulated ZnO Nanowire Photodetectors with Ultra-High Detectivity, Nat. Commun. 5, 1 (2014).

Y. Xie, L. Wei, G. Wei, Q. Li, D. Wang, Y. Chen, S. Yan, G. Liu, L. Mei, and J. Jiao, A Self-Powered UV Photodetector Based on TiO 2 Nanorod Arrays, Nanoscale Res. Lett. 8, 1 (2013).

X. Li, C. Gao, H. Duan, B. Lu, X. Pan, and E. Xie, Nanocrystalline TiO2 Film Based Photoelectrochemical Cell as Self-Powered UV-Photodetector, Nano Energy 1, 640 (2012).

W. Tian, C. Zhang, T. Zhai, S.-L. Li, X. Wang, M. Liao, K. Tsukagoshi, D. Golberg, and Y. Bando, Flexible SnO 2 Hollow Nanosphere Film Based High-Performance Ultraviolet Photodetector, Chem. Commun. 49, 3739 (2013).

Y. Zhang, T. Ji, W. Zhang, G. Guan, Q. Ren, K. Xu, X. Huang, R. Zou, and J. Hu, A Self-Powered Broadband Photodetector Based on an n-Si (111)/p-NiO Heterojunction with High Photosensitivity and Enhanced External Quantum Efficiency, J. Mater. Chem. C 5, 12520 (2017).

R. Zou, Z. Zhang, Q. Liu, J. Hu, L. Sang, M. Liao, and W. Zhang, High Detectivity Solar-Blind High-Temperature Deep-Ultraviolet Photodetector Based on Multi-Layered (L00) Facet-Oriented $β$-Ga2O3 Nanobelts, Small 10, 1848 (2014).

C. Song, N. Zhang, J. Lin, X. Guo, and X. Liu, Sb 2 O 3/Ag/Sb 2 O 3 Multilayer Transparent Conducting Films for Ultraviolet Organic Light-Emitting Diode, Sci. Rep. 7, 1 (2017).

L. Li, Y. X. Zhang, X. S. Fang, T. Y. Zhai, M. Y. Liao, H. Q. Wang, G. H. Li, Y. Koide, Y. Bando, and D. Golberg, Sb2O3 Nanobelt Networks for Excellent Visible-Light-Range Photodetectors, Nanotechnology 22, 165704 (2011).

Q. Wang, X. Yang, J. Hou, M. Huang, and Y. Zhao, Hydrothermal Synthesis of Sb2O3 Nanorod-Bundles via Self-Assembly Assisted Oriented Attachment, Appl. Surf. Sci. 257, 5857 (2011).

Y. Zhang, G. Li, and L. Zhang, Growth of Sb2O3 Nanotubes via a Simple Surfactant-Assisted Solvothermal Process, Chem. Lett. 33, 334 (2004).

K. V Divya and K. E. Abraham, Ag Nanoparticle Decorated Sb2O3 Thin Film: Synthesis, Characterizations and Application, Nano Express 1, 20005 (2020).

N. M. A. Hadia, S. Garc’ia-Granda, and J. R. Garc’ia, Structural and Optical Properties of Hydrothermally-Synthesized Single-Crystalline Sb 2 O 3 Nanowires, J. Korean Phys. Soc. 63, 2143 (2013).

Z. Deng, F. Tang, D. Chen, X. Meng, L. Cao, and B. Zou, A Simple Solution Route to Single-Crystalline Sb2O3 Nanowires with Rectangular Cross Sections, J. Phys. Chem. B 110, 18225 (2006).

L. Song, S. Zhang, and Q. Wei, Antimony Trioxide Microstructures: 3D Grass-like Architectures and Optical Properties, Chem. Eng. J. 179, 404 (2012).

S. Ge, Q. Wang, Q. Shao, Y. Zhao, X. Yang, and X. Wang, Hydrothermal Synthesis of Morphology-Controllable Sb2O3 Microstructures: Hollow Spindle-like and Cobblestone-like Microstructures, Appl. Surf. Sci. 257, 3657 (2011).

J. Wu, P. Qiao, H. Li, Y. Xu, W. Yang, F. Yang, K. Lin, K. Pan, and W. Zhou, Engineering Surface Defects on Two-Dimensional Ultrathin Mesoporous Anatase TiO 2 Nanosheets for Efficient Charge Separation and Exceptional Solar-Driven Photocatalytic Hydrogen Evolution, J. Mater. Chem. C 8, 3476 (2020).

R. Köferstein, L. Jäger, and S. G. Ebbinghaus, Magnetic and Optical Investigations on LaFeO3 Powders with Different Particle Sizes and Corresponding Ceramics, Solid State Ionics 249, 1 (2013).

T. P. McLean, The Absorption Edge Spectrum of Semiconductors, Prog. Semicond. 5, i960 (1960).

M. M. Furchi, D. K. Polyushkin, A. Pospischil, and T. Mueller, Mechanisms of Photoconductivity in Atomically Thin MoS2, Nano Lett. 14, 6165 (2014).

F. So, World Scientific Handbook Of Organic Optoelectronic Devices (Volumes 1 & 2), Vol. 12 (World Scientific, 2018).

R. Shabannia, H. A. Hassan, H. Mahmodi, N. Naderi, and H. R. Abd, ZnO Nanorod Ultraviolet Photodetector on Porous Silicon Substrate, Semicond. Sci. Technol. 28, 115007 (2013).

L. Li, P. Wu, X. Fang, T. Zhai, L. Dai, M. Liao, Y. Koide, H. Wang, Y. Bando, and D. Golberg, Single-Crystalline CdS Nanobelts for Excellent Field-Emitters and Ultrahigh Quantum-Efficiency Photodetectors, Adv. Mater. 22, 3161 (2010).

J. A. Dirksen, K. Duval, and T. A. Ring, NiO Thin-Film Formaldehyde Gas Sensor, Sensors Actuators B Chem. 80, 106 (2001).

Y. K. Su, S. J. Chang, C. H. Chen, J. F. Chen, G. C. Chi, J. K. Sheu, W. C. Lai, and J. M. Tsai, GaN Metal-Semiconductor-Metal Ultraviolet Sensors with Various Contact Electrodes, IEEE Sens. J. 2, 366 (2002).

S.-J. Young, L.-W. Ji, S.-J. Chang, and Y.-K. Su, ZnO Metal--Semiconductor--Metal Ultraviolet Sensors with Various Contact Electrodes, J. Cryst. Growth 293, 43 (2006).

S. Zhang, D. G. Zhao, D. S. Jiang, W. B. Liu, L. H. Duan, Y. T. Wang, J. J. Zhu, Z. S. Liu, S. M. Zhang, and H. Yang, Investigation of Responsivity Decreasing with Rising Bias Voltage in a GaN Schottky Barrier Photodetector, Semicond. Sci. Technol. 23, 105015 (2008).

N. H. Al-Hardan, A. Jalar, M. A. A. Hamid, L. K. Keng, N. M. Ahmed, and R. Shamsudin, A Wide-Band UV Photodiode Based on n-ZnO/p-Si Heterojunctions, Sensors Actuators A Phys. 207, 61 (2014).

D. Li, X. Sun, H. Song, Z. Li, H. Jiang, Y. Chen, G. Miao, and B. Shen, Effect of Asymmetric Schottky Barrier on GaN-Based Metal-Semiconductor-Metal Ultraviolet Detector, Appl. Phys. Lett. 99, 261102 (2011).

H. Liu, Z. Zhang, L. Hu, N. Gao, L. Sang, M. Liao, R. Ma, F. Xu, and X. Fang, New UV-A Photodetector Based on Individual Potassium Niobate Nanowires with High Performance, Adv. Opt. Mater. 2, 771 (2014).

X. Fang, L. Hu, K. Huo, B. Gao, L. Zhao, M. Liao, P. K. Chu, Y. Bando, and D. Golberg, New Ultraviolet Photodetector Based on Individual Nb2O5 Nanobelts, Adv. Funct. Mater. 21, 3907 (2011).

C. Y. Liu, B. P. Zhang, Z. W. Lu, N. T. Binh, K. Wakatsuki, Y. Segawa, and R. Mu, Fabrication and Characterization of ZnO Film Based UV Photodetector, J. Mater. Sci. Mater. Electron. 20, 197 (2009).

L. Guo, H. Zhang, D. Zhao, B. Li, Z. Zhang, M. Jiang, and D. Shen, High Responsivity ZnO Nanowires Based UV Detector Fabricated by the Dielectrophoresis Method, Sensors Actuators B Chem. 166, 12 (2012).

Y. Zou, Y. Zhang, Y. Hu, and H. Gu, Ultraviolet Detectors Based on Wide Bandgap Semiconductor Nanowire: A Review, Sensors 18, 2072 (2018).

W. Jin, Y. Ye, L. Gan, B. Yu, P. Wu, Y. Dai, H. Meng, X. Guo, and L. Dai, Self-Powered High Performance Photodetectors Based on CdSe Nanobelt/Graphene Schottky Junctions, J. Mater. Chem. 22, 2863 (2012).

Downloads

Published

2023-04-16

How to Cite

Rassam, N. T. (2023). Synthesis and Characterization of Au/ Sb 2 O 3 Ultrathin nanosheet/Au as a High-Performance UV-Photodetector. Polytechnic Journal, 12(1), 155-162. https://doi.org/10.25156/ptj.v12n1y2022.pp155-162

Issue

Section

Research Articles